SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF POLYNUCLEAR SILVER(I) COMPLEX WITH 2,2’-BIQUINOLINE
Authors
Dejan M. Gurešić
Faculty of Tehnological Sciences, University of Priština, Kosovska Mitrovica, Serbia
Sonja Ž. Đurić
Department of Chemistry, Faculty of Science, University of Kragujevac, Kragujevac, Serbia
Tina P. Andrejević
Department of Chemistry, Faculty of Science, University of Kragujevac, Kragujevac, Serbia
Mirjana M. Popsavin
Department of Chemistry, Biochemistry and Environmental Protection, Faculty of Sciences, University of Novi Sad, Novi Sad, Serbia
Biljana Đ. Glišić
Department of Chemistry, Faculty of Science, University of Kragujevac, Kragujevac, Serbia
Keywords
Silver(I) complexes, N-Heterocycles, Polynuclear complexes, Spectroscopy
Abstract
Polynuclear silver(I) complex, [Ag(NO3-O)(2,2’-bq-N,N’)]n, was synthesized by the reaction of equimolar amount of silver(I) nitrate and 2,2’-biquinoline (2,2’-bq) in ethanol at room temperature. The characterization of the complex was established on the basis of elemental microanalysis, IR, NMR (1H and 13C) and UV-Vis spectroscopic techniques. The results of spectroscopic analyses revealed that in [Ag(NO3-O)(2,2’-bq-N,N’)]n complex, 2,2’-bq ligand behaves as a chelate, while the remaining coordination sites are occupied by the oxygen atoms of two nitrates.
Published
2020/05/15
Issue
Vol. 10 No. 1 (2020)
Pages
26-30.
Section
Original Scientific Paper
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